When you say "Enterprise" Architect, you realize that includes domains of expertise outside of technology, right? Just making sure you're considering the requirement for business process and information architecture in addition to the technology end.
Also, within the technology domain, you'll also need to provide coverage as an Enterprise Architect for areas significantly outside of development. Off the top of my head, this would include the Infrastructure, Security, Storage, Management & Monitoring, and Configuration areas.
I'd recommend you check out a couple of sources for a view of what's involved at the enterprise. Try the Zachman Framework at
www.zifa.com and TOGAF at
www.togaf.org. A couple of books that have some relevance are "A Practical Guide to Enterprise Architecture" <McGovern, Ambler, et al, ISBN: 0-13-141275-2> and "Enterprise System Architectures" <Goodyear, ISBN: 0-8493-9836-3>.
It's very possible that's what you want. And it's very possible that you really want to pursue an architecture career within a technology area instead. In the latter is the case, you don't want to bill yourself as an Enterprise Architect. This could lead to some interesting interviews.
PS - Sparx's Enterprise Architect, as a point of reference, is a fabulous modeling and code engineering tool, but isn't very comprehensive as an "enterprise" scale tool. I think the name's a bit optimistic for that and the UML, while helpful, isn't enough to capture everything in the enterprise. To be fair too though, there aren't very many tools that truly deal at an enterprise level; and none that I know of anywhere *close* to EA's price range.